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Valero is the best-in-class producer of fuels and products that are essential to modern life. We are the largest global independent refiner and Americas largest producer of renewable fuels, advancing the. Not registered yet? Pay your bill, view recent activity, activate your card, and more with Valero Self Serve - it's free. Valero is the worlds largest independent refiner and the worlds largest producer of low-carbon transportation fuels. Valero provides essential fuels and products which fuel modern life; today and. Please enable JavaScript in your browser to sign-in. Sign-In Now!